Nucleophilic reactivity of the peroxide anion in aqueous-alcoholic solutions in the presence of detergents |
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| Authors: | L. N. Vakhitova A. V. Skrypka K. V. Bogutskaya N. A. Taran A. F. Popov |
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| Affiliation: | (1) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Vul. R. Luxemburg, 70, Donets’k, 83114, Ukraine |
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| Abstract: | The reactivity of hydroxide and peroxide anions with 4-nitrophenyl N,N-dimethylcarbamate in aqueous-alcoholic detergent media and in “oil in water” microemulsions has been studied. Aqueous-alcoholic solutions of cationic (CTAB) and neutral (Triton X-100) surface active substances have promise for decomposition of substrates by a nucleophilic mechanism. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 6, pp. 358–363, November–December, 2007. |
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| Keywords: | surface active substances microemulsion hydrogen peroxide nucleophilic substitution |
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