Selective syntheses of [7]-[12]cycloparaphenylenes using orthogonal suzuki-miyaura cross-coupling reactions |
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| Authors: | Evan R Darzi Thomas J Sisto Ramesh Jasti |
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| Institution: | Department of Chemistry, Boston University , 24 Cummington Street, Boston, Massachusetts 02215, United States. |
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| Abstract: | The divergent, selective syntheses of 7]-12]cycloparaphenylenes have been accomplished utilizing sequential, orthogonal Suzuki-Miyaura cross-coupling reactions from two late-stage intermediates. Quantum yields decrease dramatically as cycloparaphenylene size decreases, highlighting the unique photophysical behavior of the smaller cycloparaphenylenes. |
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