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Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes
Authors:Cai-Yan Gao  Xin He  Liang Zhao  Mei-Xiang Wang
Affiliation:The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
Abstract:A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.
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