Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes |
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Authors: | Cai-Yan Gao Xin He Liang Zhao Mei-Xiang Wang |
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Affiliation: | The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China. |
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Abstract: | A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized. |
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