Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology |
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| Authors: | Volodymyr Bon Volodymyr Senkovskyy Irena Senkovska Stefan Kaskel |
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| Affiliation: | Department of Inorganic Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany. |
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| Abstract: | Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr(4+) or Hf(4+) source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology. |
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