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Regioselective Addition of Dithiophosphinic Acids to Vinyl Sulfides and Selenides: An Efficient Route Toward Functional Dithiophosphinates |
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| Authors: | Ludmila A Oparina Alexander V Artem'ev Nikita A Kolyvanov Oksana V Vysotskaya Nataliya A Chernysheva Vladimir I Smirnov Tatyana N Borodina Nina K Gusarova Boris A Trofimov |
| Abstract: | Earlier unknown S‐1‐(organosulfanyl)ethyl]‐ and S‐1‐(organoselenyl)ethyl] dithiophosphinates were synthesized in 85–97% yields by regioselective addition of dithiophosphinic acids to diverse vinyl sulfides and selenides under mild conditions (ambient temperature, Et2O, 3 h). |
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