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Crystal growth of cyclodextrin‐based metal‐organic framework with inclusion of ferulic acid
Authors:Wataru Michida  Masato Ezaki  Mina Sakuragi  Guoqing Guan  Katsuki Kusakabe
Abstract:The crystallization of γ‐cyclodextrin‐based metal‐organic framework (CD‐MOF) with inclusion of ferulic acid (FA) was carried out through vapor diffusion of methanol to the aqueous solution of γ‐cyclodextrin (γ‐CD), KOH and FA. Although the crystallization of pure CD was limited in highly basic solution of KOH (pH>13.0), the CD‐MOF with inclusion of FA (FA/CD‐MOF) was able to be formed at pH 6.8 after the neutralization of KOH by FA. The inclusion behavior of FA in CD‐MOF was studied by using differential scanning calorimetry. The data indicate the formation of the stable association between FA and γ‐CD in FA/CD‐MOF.
Keywords:metal‐organic framework  cyclodextrin  ferulic acid  adsorbent  porous material
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