New method for the synthesis of σ-β-ketovinyl derivatives of cyclopentadienyliron dicarbonyl |
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Authors: | A N Nesmeyanov M I Rybinskaya E A Petrovskaya T V Popova |
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Institution: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions A new method was developed for the synthesis of -RCOCH=CHFe(CO)2C5H5- by the reaction of -iodovinyl ketones with Fe(CO)2C5H5- ]2. In this case it was demonstrated for the first time that the reaction of organic haloderivatives with Fe(CO)2C5H5- ]2 can be used for the synthesis of -RFe(CO)2C5H5- .Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1646–1647, July, 1972. |
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