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New method for the synthesis of σ-β-ketovinyl derivatives of cyclopentadienyliron dicarbonyl
Authors:A N Nesmeyanov  M I Rybinskaya  E A Petrovskaya  T V Popova
Institution:(1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR
Abstract:Conclusions A new method was developed for the synthesis of sgr-RCOCH=CHFe(CO)2C5H5-pgr by the reaction ofbeta-iodovinyl ketones with Fe(CO)2C5H5-pgr]2. In this case it was demonstrated for the first time that the reaction of organic haloderivatives with Fe(CO)2C5H5-pgr]2 can be used for the synthesis of sgr-RFe(CO)2C5H5-sgr.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1646–1647, July, 1972.
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