Synthesis,characterization and fluorescence behavior of new fluorescent probe phthalocyanines bearing coumarin substituents |
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Authors: | Meryem Ç amur,Mustafa Bulut,Mehmet Kandaz,Orhan Gü ney |
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Affiliation: | 1. Department of Chemistry, Marmara University, 34722 Kad?köy-Istanbul, Turkey;2. Department of Chemistry, Sakarya University, 54140 Esentepe, Sakarya, Turkey;3. Department of Chemistry, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey |
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Abstract: | In this study, we report a new ligand, 6-hexyloxy-3-[p-(3′,4′-dicyanophenoxy)phenyl]coumarin, and its fluorescent tetrasubstituted phthalocyanines {M[Pc(OBzCou)4], M = 2H, Zn(II), Co(II); Bz: Benzene}. The effect of the coumarin derivative on the intensity of the fluorescence spectra of the metal-free (H2Pc) and zinc phthalocyanine (ZnPc) derivatives was investigated. The change of the emission properties of both the coumarin moieties and the phthalocyanine core in the presence of the metal ion and the ring-opening reaction of the coumarin were studied by means of steady-state fluorescence spectroscopy. The radiative decay of the Pcs and the treated coumarin substituents bound to the Pcs was examined. The novel chromogenic compounds were characterized by elemental analysis, 1H NMR, 13C NMR, Maldi-TOF, IR and UV–Vis spectral data. The photophysical properties of the Pcs are extensively affected by their state of aggregation: in particular, dimerization and aggregation result in a remarkable modification of the absorption and emission bands and may induce significant quenching of the usually strong Pc fluorescence. The electronic spectra exhibit a band of coumarin identity together with characteristic Q and B bands of the phthalocyanine core. |
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Keywords: | Phthalocyanines Fluorescence Coumarin derivatives Aggregation Cobalt Zinc |
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