Thermoanalytical investigations of some industrial wastes produced in steel works |
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Authors: | M Sebastian J R Dobosz |
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Institution: | (1) Institute of Environment Protection Engineering, Technical University of Wroc aw, Poland |
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Abstract: | The experiments involves three types of industrial wastes produced by iron works, which create serious hazards to the natural environment: (1) paint-shop sludge, (2) oil-polluted diatomite, and (3) oil-polluted scale. The choice of an appropriate and safe storage method should be based on extensive physicochemical examination.DTA, in combination with other data, allows characterization of the combustible properties of wastes. Thermoanalytical measurements were carried out in a dynamic air atmosphere. Enthalpy values were calculated from peak areas of DTA curves. Thermoanalytical data were compared with calorimetric results obtained with an oxygen bomb.
Zusammenfassung Drei Arten industrieller Abtälle eines Stahlwerks, die schwere Umweltbelastungen darstellen, wurden untersucht: (1) Lackiererei-Schlamm, (2) ölhaltiger Diatomit, (3) ölhaltiger Kesselstein. Geeignete sichere Deponien setzen ausführliche physikalisch-chemische Untersuchungen voraus. DTA in Kombination mit anderen Untersuchungen erlaubt die Charakterisierung der Verbrennungseigenschaften der Abfälle. Die thermoanalytischen Untersuchungen erfolgten im Luftstrom, die Verbrennungswärmen wurden aus den DTA-peak-Flächen berechnet. Die Ergebnisse werden mit denen kalorimetrischer Messungen in einer Sauerstoffbombe verglichen.
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![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![zcy](/content/n5w34778m2700134/xxlarge1079.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![jcy](/content/n5w34778m2700134/xxlarge1081.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![khcy](/content/n5w34778m2700134/xxlarge1093.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) . ![Tcy](/content/n5w34778m2700134/xxlarge1058.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![zcy](/content/n5w34778m2700134/xxlarge1079.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![bcy](/content/n5w34778m2700134/xxlarge1073.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![zcy](/content/n5w34778m2700134/xxlarge1079.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![ucy](/content/n5w34778m2700134/xxlarge1091.gif) ![khcy](/content/n5w34778m2700134/xxlarge1093.gif) . ![Zcy](/content/n5w34778m2700134/xxlarge1047.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![ecy](/content/n5w34778m2700134/xxlarge1101.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![softcy](/content/n5w34778m2700134/xxlarge1100.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![bcy](/content/n5w34778m2700134/xxlarge1073.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![shchcy](/content/n5w34778m2700134/xxlarge1097.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![Dcy](/content/n5w34778m2700134/xxlarge1044.gif) ![Tcy](/content/n5w34778m2700134/xxlarge1058.gif) . ![Tcy](/content/n5w34778m2700134/xxlarge1058.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![bcy](/content/n5w34778m2700134/xxlarge1073.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![vcy](/content/n5w34778m2700134/xxlarge1074.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![acy](/content/n5w34778m2700134/xxlarge1072.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![tcy](/content/n5w34778m2700134/xxlarge1090.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![chcy](/content/n5w34778m2700134/xxlarge1095.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) , ![pcy](/content/n5w34778m2700134/xxlarge1087.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![ucy](/content/n5w34778m2700134/xxlarge1091.gif) ![iecy](/content/n5w34778m2700134/xxlarge1077.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ycy](/content/n5w34778m2700134/xxlarge1099.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![kcy](/content/n5w34778m2700134/xxlarge1082.gif) ![icy](/content/n5w34778m2700134/xxlarge1080.gif) ![scy](/content/n5w34778m2700134/xxlarge1089.gif) ![lcy](/content/n5w34778m2700134/xxlarge1083.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![rcy](/content/n5w34778m2700134/xxlarge1088.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![dcy](/content/n5w34778m2700134/xxlarge1076.gif) ![ncy](/content/n5w34778m2700134/xxlarge1085.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![bcy](/content/n5w34778m2700134/xxlarge1073.gif) ![ocy](/content/n5w34778m2700134/xxlarge1086.gif) ![mcy](/content/n5w34778m2700134/xxlarge1084.gif) ![bcy](/content/n5w34778m2700134/xxlarge1073.gif) .
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