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Diffusion mechanism during the swelling hidroxy-methyl cellulose membrane formation
Authors:Heriberto Espinoza-Gomez  Raudel Ramos-Olmos  Cesar Garcia-Rios  Shui Wai Lin  Eduardo Rogel-Hernandez  Ana Ames-Lopez
Institution:(1) Facultad de Ciencias Químicas e Ingeniería, Universidad Autónoma de Baja California-Tijuana, Calzada Tecnológico, 14418 Tijuana, B.C., México;(2) Centro de Graduados e Investigación del Instituto Tecnológico de Tijuana, Apdo. Postal 1166 Tijuana, B.C., México
Abstract:The conduction properties of HMC polymer gel prepared by the phase inversion method were investigated through the diffusion coefficient in order to confirm the conduction mechanism. The solution introduced in the polymer is stored in the pores and then penetrates into the polymer chains. For swelling the polymer network. A model describing the swelling hidroxy-methyl cellulose is presented. The model is used to predict the type liquid–liquid phase separation (instantaneous or delayed) that occurs when HMC-PVPD-Solvent-Water casting solutions are immersed in a gelation bath. The model includes the thermodynamic interactions parameters and the transport parameters. The predictions of the model agree with the experimental observations.
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