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Magnetic and Raman Scattering Studies on Intercalation Compounds FexNbS2
Authors:Mikio Koyano  Hirokazu Watanabe  Yasuhisa Yamamura  Toshihide Tsuji  Shin'ichi Katayama
Institution:1. School of Materials Science;2. Center for New Materials , Japan Advanced Institute of Science and Technology , Tatsunokuchi, Ishikawa , 923-1292 , JAPAN;3. Development Department, Research &4. Development Design , Noritake Co., Limited , Miyoshi, Aichi , 470-0293 , JAPAN
Abstract:Abstract

Raman scattering spectra and magnetic susceptibility are measured in intercalation compounds FexNbS2 (0.159≤x≤0.325). A strong modification of Raman spectra is observed in a sample with x=0.239 (~ 0.25) which is accompanied by 2a × 2a structural change and antiferromagnetic ordering. Some correlations between magnetic ordering (antiferromagnetic or spin glass) and structural change are also discussed for wide range of Fe contents x.
Keywords:Intercalation  FcxNbS2  Superstructure  Raman scattering  Magnetic susceptibility  Magnetic interaction
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