One-pot Synthesis and Characterization of Poly(meta-aryl sulfide sulfone imide imide) |
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| Authors: | Mei-Lin Zhang Xiao-Jun Wang Gang Zhang Sheng-Ru Long Jie Yang |
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| Institution: | 1. College of Chemistry , Sichuan University , Chengdu, P. R. China;2. Institute of Materials Science and Technology, Sichuan University , Chengdu, P. R. China;3. Institute of Materials Science and Technology, Sichuan University , Chengdu, P. R. China;4. State Key Laboratory of Polymer Materials Engineering of China , Sichuan University , Chengdu, P. R. China |
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| Abstract: | Poly(meta-aryl sulfide sulfone imide imide) (m-PASSII) was synthesized by one-pot process using 4-chlorophthalic anhydride, 3,3′-diamino diphenyl sulfone and sodium sulfide (Na2S· xH2O) as starting materials in N-methyl-2-pyrrolidone at atmospheric pressure. The intrinsic viscosity of m-PASSII was obtained with optimum synthesis conditions is 0.21-0.27 dl/g. The polymer and the separated intermediates which generated during the synthesis process were characterized by elemental analysis, FT-IR spectrum, 1H-NMR spectrum, X-ray diffraction, DSC, TGA and dissolvability experiment. The polymer is found to have excellent thermal performance with glass transition temperature (T g ) of 224°C and initial degradation temperature (T d ) of 441°C. Moreover, the polymer is dissolvable in strong polar solvents. |
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| Keywords: | Poly(arylene sulfide) one-pot synthesis poly(meta-aryl sulfide sulfone imide imide) intermediates characterization |
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