Perylene as a visible light photoredox catalyst for photoinduced electron transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization of MMA |
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Authors: | Bin-Hong He Mang Lu Cai-Xia Yang Enxiang Liang |
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Affiliation: | 1. College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan Province, China;2. School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi Province, China |
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Abstract: | AbstractThe organic photocatalyst, perylene, was used to mediate photoinduced electron transfer (PET) reversible addition-fragmentation chain transfer polymerization (RAFT) of methyl methhacrylate (MMA) under light irradiation in N,N-dimethylformamide (DMF) at 25°C with 4-cyanopentanoic acid dithiobenzoate (CPADB) as chain transfer agent (CTA). Kinetic studies confirmed that the polymerization obeyed the first order kinetic m'odel. The production of PMMAs with a good control of molecular weights (Mn,GPC) and narrow polymer molecular weight distribution (Mw/Mn) were obtained. It is found that well-controlled PET RAFT polymerization of MMA can be manipulated even with the amount of perylene decreasing to ppm level. No polymer was obtained in the absence of light irradiation, implying that the model of PET RAFT polymerization of MMA is an ideal light “on”-“off” switchable system. Furthermore, the speed of PET RAFT polymerization of MMA was also finely tunable by the external light irradiation intensity. The resultant PMMA macro-CTA was characterized by 1H nuclear magnetic resonance spectrum (1H NMR) and gel permeation chromatography (GPC). The accessibility of the high end group fidelity was further demonstrated by chain extension experiments. |
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Keywords: | Perylene controlled/‘living’ photoradical polymerization photoelectron transfer reversible addition-fragmentation chain transfer photocatalyst |
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