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Synthesis and Polymerization Reactions of Cyclic Imino Ethers. 4. Aromatic Poly(ester amide)s of the AA+BB Type on the Basis of 2-Oxazolines
Authors:J. Lustoň  J. Kronek  I. Janigová
Affiliation:1. Polymer Institute of the Slovak Academy of Sciences, Centre of Excellence GLYCOMED , Bratislava, Slovakia;2. Polymer Institute of the Slovak Academy of Sciences , Bratislava, Slovakia
Abstract:Poly(ester amide)s were prepared by thermally initiated polymerization from two aromatic bis(2-oxazoline)s and four aromatic dicarboxylic acids. Polymerizations were performed in bulk and in solution. The structure of the polymers formed was confirmed by spectral analysis. The synthesis is limited by the thermal stability of the starting compounds. Limitation of the solution polymerization is the solubility of the starting compounds and the products in the solvent used. The prepared polymers have very good thermal properties.
Keywords:Addition polymerization  high temperature materials  ring opening polymerization  thermal initiation  poly(ester amide)
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