Compatible Polyethylene/Polyvinyl Chloride Particle Hybrids Prepared by in‐situ Polymerization |
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| Authors: | Xin Wang Jin‐Yong Dong |
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| Institution: | 1. Key Laboratory of Rubber‐Plastics , Ministry of Education, Qingdao University of Science and Technology , Qingdao, China;2. Polymer BIN Fusion Research Team, Department of Polymer Science and Technology , Chonbuk National University , Jeonju, Jeonbuk, South Korea;3. Institute of Chemistry, Chinese Academia of Science , Beijing, China |
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| Abstract: | Polyethylene/polyvinyl chloride (PE/PVC) hybrids were successfully prepared by a polymerization‐filling method. The catalyst for ethylene polymerization was supported on PVC particles, and ethylene was then polymerized in‐situ on the surface of the activated PVC. PVC particles could be well segmented and dispersed during in‐situ polymerization, and the prepared hybrids had an additional tangent peak between the glass transitions of polyethylene and PVC, indicating the formation of a compatible interlayer between nascent polyethylene and PVC during polymerization. |
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| Keywords: | hybrid in‐situ polymerization compatibility immiscible polymers |
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