Intelligent Sugar Complexes |
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| Authors: | Shigenobu Yano Masako Nakagoshi Akemi Teratani Masako Kato Tomoaki Tanase Yasuhiro Yamamoto |
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| Affiliation: | 1. Department of Chemistry , Nara Women's University, Nara , Nara , 630 , Japan;2. Department of Chemistry , Toho University , Funabashi, Chiba , 274 , Japan |
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| Abstract: | Abstract The structure of [Co(L-Rha)3-mn)]Br2.2CH3OH, where (Rhah-tren is tris(N-rhamnosyl-2-aminoethyl)amine, was elucidated by X-ray crystallography, which confirmed the unprecedented configurational inversion of [Co((Rha)3-tren)]2+, around the metal center reversibly by an addition and a removal of sulfate. |
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