Enantioselective synthesis of alpha-terpineol and nephthenol by intramolecular acyloxazolidinone enolate alkylations |
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| Authors: | Jin Yinghua Coates Robert M |
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| Institution: | Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, IL 61801, USA. |
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| Abstract: | Enolate anions generated from norterpenyl bromides bearing oxazolidinone chiral auxiliaries at the chain termini underwent efficient, stereo-biased cyclizations to form 6- and 14-membered rings in novel synthetic routes to alpha-terpineol and nephthenol enantiomers. |
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