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Sol-Gel Processing of Functional and Structural Ceramic Oxide Fibers
Authors:Glaubitt  Walther  Watzka  Winfried  Scholz  Hermann  Sporn  Dieter
Affiliation:(1) Fraunhofer-Institut für Silicatforschung, Neunerplatz 2, D-97082 Würzburg, Germany
Abstract:Structural ceramic oxide fibers like α-Al2O3, MgAl2O4 (spinel), Y3Al5O12 (YAG) and eutectic Al2O3−Y3Al5O12 as well as the functional Pb(Zr1−xTix)O3 (PZT) fibers were successfully prepared by sol-gel processing. All precursors are based on metal oxohydroxopropionates. A comparative study of sol-gel routes leading to spinnable sols demonstrates the key role of propionic acid as an excellent agent for controlling hydrolysis and condensation reactions.
Keywords:ceramic fibers  spinnability  sol-gel
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