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Trifluoromethylation and pentafluorophenylation of enamines |
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| Authors: | A D Dilman V V Gorokhov P A Belyakov M I Struchkova V A Tartakovsky |
| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
| Abstract: | A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to α-CF3-and α-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1466–1468, August, 2007. |
| Keywords: | silanes iminium cations pentacoordinate silicon amines enamines organosilicon compounds organofluorine compounds |
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