Fullerenyl boronic esters: ferric perchlorate-mediated synthesis and functionalization |
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| Authors: | Li Fa-Bao You Xun Liu Tong-Xin Wang Guan-Wu |
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| Affiliation: | Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. |
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| Abstract: | Fullerenyl boronic esters have been prepared by a ferric perchlorate-promoted reaction of [60]fullerene with various arylboronic acids. The obtained fullerenyl boronic esters could undergo further functionalization with diols to afford C(60)-fused dioxane/dioxepane derivatives. A possible reaction mechanism for the formation of fullerenyl boronic esters has been proposed. |
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