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Fullerenyl boronic esters: ferric perchlorate-mediated synthesis and functionalization
Authors:Li Fa-Bao  You Xun  Liu Tong-Xin  Wang Guan-Wu
Affiliation:Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Abstract:Fullerenyl boronic esters have been prepared by a ferric perchlorate-promoted reaction of [60]fullerene with various arylboronic acids. The obtained fullerenyl boronic esters could undergo further functionalization with diols to afford C(60)-fused dioxane/dioxepane derivatives. A possible reaction mechanism for the formation of fullerenyl boronic esters has been proposed.
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