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| 三水合硝酸钪18-冠-6配合物的合成及其晶体结构 | |
| 引用本文： | 金钟声,刘永盛,张树功,于凤兰,倪嘉缵. 三水合硝酸钪18-冠-6配合物的合成及其晶体结构[J]. 化学学报, 1987, 45(11): 1048-1052 |
| 作者姓名： | 金钟声 刘永盛 张树功 于凤兰 倪嘉缵 |
| 作者单位： | 中国科学院长春应用化学研究所 |
| 摘 要： | 报道了[Sc(NO3)3(OH2)3].(18-冠-6)的合成及其晶体结构.Sc(III)离子同三个双齿配体硝酸根与三个水分子氧配位,构成九配位的配合物.配位多面体是稍有扭曲的单帽四方反棱柱.配位水分子的六个氢原子分别与上下两层冠醚环上的氧原子生成氢键,形成多层夹心分子缔合物. |
| 关 键 词： | 晶体结构测定 冠式化合物 硝酸 化学键 水络合物 络合物化学 夹心化合物 钪络合物 |
Synthesis and crystal structure of [Sc(NO3)3(OH2)3].(18-crown-6) |
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| JIN ZHONGSHENG,LIU YONGSHENG,ZHANG SHUGONG,YU FENGLAN,NI JIAZUAN. Synthesis and crystal structure of [Sc(NO3)3(OH2)3].(18-crown-6)[J]. Acta Chimica Sinica, 1987, 45(11): 1048-1052 | |
| Authors: | JIN ZHONGSHENG LIU YONGSHENG ZHANG SHUGONG YU FENGLAN NI JIAZUAN |
| Abstract: | The crystal and mol. structure of [Sc(NO3)3(OH2)3].18-crown-6 (I) was determine from single crystal x-ray diffraction. I crystd. in the orthorhombic space group Pna21 with Z = 4, a 15.300(3), b 10.879(3), c 14.052(3) ? R = 0.0739 for 975 reflections. The Sc3+ ion is 9-coordinate, being bonded to 3 bidentate nitrate groups and to 3 H2O mols. in a capped square antiprism. There are 6 H atoms in 3 coordinated H2O mols., 3 of them are bonded to 3 O atoms in the above crown ether ring; the rest of them are bonded to the lower layer crown ether ring. I forms a multilayer sandwich structure. The preparation of I is given. |
| Keywords: | CRYSTAL STRUCTURE DETERMINATION CROWN ETHER COMPOUNDS NITRIC ACID CHEMICAL BONDS AQUO COMPLEX COORDINATE CHEMISTRY SANDWICH COMPOUNDS SCANDIUM COMPLEX |
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