| H_3PO_4－i－C_3H_7OAl－H_2NCH_2CH_2NH_2－HOC |
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| 引用本文： | 高秋明,李守贵,徐如人. H_3PO_4－i－C_3H_7OAl－H_2NCH_2CH_2NH_2－HOC[J]. 高等学校化学学报, 1995, 0(3) |
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| 作者姓名： | 高秋明 李守贵 徐如人 |
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| 作者单位： | 吉林大学无机合成开放实验室 |
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| 摘 要： | 以乙二胺为模板剂，采用Ｈ_３ＰＯ_４－ｉ－Ｃ_３Ｈ_７ＯＡｌ－Ｈ_２ＮＣＨ_２ＣＨ_２ＮＨ_２－ＨＯＣＨ_２ＣＨ_２ＯＨ非水体系，首次合成了ＡｌＰＯ_４－１２分子筛。研究了反应物配比、酸碱度及磷源、铝源等水热晶化条件对产物物相的影响，用ＸＲＤ、ＩＲ、ＳＥＭ及ＴＧ－ＤＴＡ等对产物进行了表征，对非水体系生成的ＡｌＰＯ_４－１２中有机模板剂乙二胺的化学环境进行了研究，认为乙二胺在晶体中以两种环境存在：一部分与骨架作用力较弱；另一部分与骨架以较强的氢键相作用。
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| 关 键 词： | 磷酸铝分子筛，非水体系，水热合成，结构表征，AlPO_4－12 |
Synthesis and Characterization of AlPO_4-12 Molecular Sieve from H_3PO_4-i-C_3H_7OAl-H_2NCH_2CH_2NH_2-HOCH_2CH_2OH System |
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| GAO Qiu-Ming,LI Shou-Gui, XURu-Ren. Synthesis and Characterization of AlPO_4-12 Molecular Sieve from H_3PO_4-i-C_3H_7OAl-H_2NCH_2CH_2NH_2-HOCH_2CH_2OH System[J]. Chemical Research In Chinese Universities, 1995, 0(3) |
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| Authors: | GAO Qiu-Ming LI Shou-Gui XURu-Ren |
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| Abstract: | Hydrothermal crystallization of aluminophosphate molecule sieve(ALPO_4-12)was carried out from H_3PO_4-i-C_3H_7OAl-H_2NCH_2CH_2NH_2-HOCH_2CH_2OH system,Using aluminum triisopropoxide and phosphorous acid (85 wt%)as the aluminum and phosphoroussources.The influences of some main factors(pH,the ratio of P_2O_5/Al_2O_3 and the aluminum and phosphorous sources,etc.) on the resulting structure were studied.The product was characterized by means of X-ray powder diffraction,scanning electron mieroscope,infrared spectroscopy,differential analysis and thermogravimetric analysis. The results of investigating the crystallization of AlPO_4-12 from non-aqueous system were preliminarily summarized.We found that the organic template,H_2NCH_2CH_2NH_2,had two different kinds of environments:one interacted with the skelton by weak hydrogen-bond,the others interacted with the skelton by strong hydrogen-bond. |
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| Keywords: | Aluminophosphate molecule sieve AlPO_4-12 Non-aqueous system Hydrothermal synthe3sis Characterization. |
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