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Phenylsulfonyl as a directing group for nitrile oxide cycloadditions and mCPBA epoxidations |
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| Authors: | Jeffrey D. Butler |
| Affiliation: | Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA |
| Abstract: | An unexpected selectivity trend in the nitrile oxide cycloaddition and epoxidation reactions of 4,4-disubstituted cyclopentenes is reported. A variety of facially distinct, ‘X-’ and ‘Y-substituted’ cyclopentenes were investigated. |
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