The first synthesis of marine sesterterpene (+)-scalarolide |
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| Authors: | Xiang-Jian Meng Wei-Ping Deng |
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| Affiliation: | School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China |
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| Abstract: | The synthesis of the first example of C12 oxygenated marine scalaranic sesterterpenes (+)-scalarolide was achieved through three key steps including the ring-opening rearrangement of epoxide, stereoselective Diels-Alder addition and one-pot γ-butenolide formation process, and the absolute configuration of natural scalarolide was confirmed. |
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