Bound ro-vibronic states of triplet H3(+) |
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Authors: | Friedrich O Alijah A Xu Z Varandas A J |
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Institution: | Fakult?t für Chemie, Universit?t Bielefeld, 33615 Bielefeld, Germany. |
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Abstract: | On the basis of a new, highly accurate potential energy hypersurface for the lowest triplet state of H+3, (3)Sigma(+)(u), the bound ro-vibronic states are calculated for J=5. Since the potential has very shallow minima, those states exist only up to single vibrational excitation. The symmetry properties of the ro-vibrational states are investigated. Further, it is demonstrated that the first excited triplet state, which intersects conically with the (3)Sigma(+)(u) state, has no effect on the reported ro-vibrational energies. |
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