Hexa(1-vinylimidazole)Co(II) perchlorate |
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Authors: | Yakup Baran Wolfgang Linert |
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Institution: | (1) Department of Chemistry, Karaelmas University, 67100 Zonguldak, Turkey;(2) Institution of Inorganic Chemistry, Technical Universit of Wien, Wien, Austria |
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Abstract: | A new cobalt(II) complex of 1-vinylimidazole (vinim) has been synthesized as the perchlorate salt and structurally characterized. The molecular structure of the complex exhibits six coordination in which the geomety is a distorted octahedron. The vinylimidazole ring is coordinated through the imidazole nitrogen, as expected from earlier spectroscopic studies of related adducts. The space group is P21/n, with a = 8.512(2), b = 13.857(2), c = 16.146(2) Å, = 96.30(1)°, V = 989.31 Å3, and Z = 2. |
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Keywords: | d-block metals imidazole derivatives copper(II) |
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