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Incomplete ferroelectricity in SrTi 18O 3
Authors:A Bussmann-Holder  A R Bishop
Institution:(1) Max-Planck-Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, Germany;(2) Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
Abstract:Motivated by recent experiments demonstrating suppression of ferroelectricity with pressure in SrTi18O3, the dynamics of the phase transition mechanism are reinvestigated within a nonlinear polarizability model. For temperatures far above the phase transition polar micro domains are formed which increase in size with decreasing temperature to freeze out at Tc without forming long range order. Experimentally, soft mode dynamics are simultaneously observed, evidencing that displacive and order/disorder features coexist. In the ferroelectric phase both components persist whereby an incomplete and inhomogeneous ferroelectric state is formed.
Keywords:77  80  Bh Phase transitions and Curie point  77  80  -e Ferroelectricity and antiferroelectricity  05  45  -a Nonlinear dynamics and chaos
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