Reactions of the dinitrogen complextrans-[ReCl(N2)(dppe)2] with thiolate compounds and with carbon bisulphide |
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| Authors: | Armando J L Pombeiro Raymond L Richards |
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| Institution: | (1) Centro de Química Estrutural, Complexe I, Institute Superior Técnico, Av. Rovisco Pais, 1096 Lisboa, Codex, Portugal;(2) AFRC Unit of Nitrogen Fixation, University of Sussex, BNI 9RQ Falmer, Brighton, UK |
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| Abstract: | Summary The complextrans-ReCl(N2)(dppe)2], (1) reacts with the thiolate salts LiSC6H4Me-4], TlSC6H4Me-4] and Pb(SBu-t)2] to yield ReCl(SC6H4Me-4)(dppe)2], Re(SC6H4Me-4) (dppe)2] and {ReO(dppe)}2( -Cl)(-S)(-SBu-t)] (tentative formulation), respectively. The ReCl( 2-CS2)(dppe)2] complex appears to be formed by reaction of (1) with CS2. |
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