Ring opening polymerization of adipic anhydride initiated by dibutylmagnesium initiator |
| |
| Authors: | Zhen Li Jianyuan Hao Minglong Yuan Xianmo Deng |
| |
| Affiliation: | Chengdu Institute of Organic Chemistry, Academia Sinica, P.O. Box 415, Chengdu 610041, China |
| |
| Abstract: | The ring opening polymerization of adipic anhydride (AA) initiated by dibutylmagnesium has been investigated in solution and in bulk. The results indicate that dibutylmagnesium is quite effective for the ring opening polymerization of AA. The polymer has been characterized by 1H-NMR, IR and DSC. The end group analysis suggests that the AA polymerization might proceed through the “coordination-insertion” mechanism based on the acyl-oxygen cleavage of the AA ring. |
| |
| Keywords: | Ring opening polymerization Dibutylmagnesium initiator Polyanhydride Adipic anhydride |
| 本文献已被 ScienceDirect 等数据库收录！ |
