Synthesis, structure and dielectric properties of Ba1-xSrxMyTi1-yO3 (M = Zr, Sn) |
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Authors: | Shiwen Ding Yongqing Zhai Ying Li Zhiqiang Wang Jinlong Li |
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Affiliation: | 1. Department of Chemistry, Hebei University, 071002, Baoding, China
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Abstract: | A series of Ba1-xSrxMyTi1-yO3 (M = Zr, Sn, 0?x?0.4, 0?y?0.3) solid solutions were synthesized with the soft chemical method below 100 °C. XRD pattern and cell parameters-composition figures of the prepared powder demonstrate that they are completely miscible solid solutions based on BaTiO3. Furthermore, TEM shows that they have a shape of uniform, substantially spherical particles with an average particle size of 70 nm in diameter. The sintered ceramics of the powder doped with Sr2+and Zr4+ or Sn4+ have dielectric constant eight times higher and dielectric loss thirty per cent lower than those of pure BaTiO3 phase at room temperature. |
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