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柴油机燃烧过程羰基化合物演变历程研究
引用本文:张华伟,宋崇林,吕刚,宋金瓯,裴毅强.柴油机燃烧过程羰基化合物演变历程研究[J].工程热物理学报,2011(7).
作者姓名:张华伟  宋崇林  吕刚  宋金瓯  裴毅强
作者单位:天津大学内燃机燃烧学国家重点实验室;
基金项目:国家自然科学基金资助项目(No.51076116); 天津市应用基础及前沿技术研究计划(No.09JCZDJC25100)
摘    要:利用全气缸采样平台,结合高效液相色谱(HPLC)技术,研究了柴油机燃烧过程中单循环燃烧中间产物羰基化合物的演变历程。结果表明,甲醛在燃烧过程中呈先增加而后迅速降低的变化过程,最大值出现在放热率峰值之前。C2-C4羰基化合物在燃烧放热率最高点之前急剧降低,之后开始升高,并在燃烧后期趋于稳定。此外,在任意燃烧阶段,随着碳原子数的增加,羰基化合物的量都逐渐降低。

关 键 词:柴油机  燃烧过程  HPLC  羰基化合物  演变历程  

The Evolution History of Carbonyl Compounds During Diesel Engine Combustion Process
ZHANG Hua-Wei SONG Chong-Lin LU Gang SONG Jin-Ou PEI Yi-Qiang.The Evolution History of Carbonyl Compounds During Diesel Engine Combustion Process[J].Journal of Engineering Thermophysics,2011(7).
Authors:ZHANG Hua-Wei SONG Chong-Lin LU Gang SONG Jin-Ou PEI Yi-Qiang
Institution:ZHANG Hua-Wei SONG Chong-Lin LU Gang SONG Jin-Ou PEI Yi-Qiang (State Key Laboratory of Engines,Tianjin University,Tianjin 300072,China)
Abstract:With total cylinder dumping system,the evolution history of carbonyl compounds during the diesel engine combustion process at single cycle was investigated by using high performance liquid chromatograph technology(HPLC).The analytical results indicate that the formaldehyde mass first increase and then decrease rapidly,and the maximum value occurs before the peak level of heat release rate(HRR).The C2-C4 carbonyl compounds decreased rapidly before the peak level of HRR,and then increased gradually and stabil...
Keywords:diesel  combustion process  HPLC  carbonyl compounds  evolution history  
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