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Palladium(II) and platinum(II) complexes in MN2x2 chromophores |
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| Authors: | A. Benedetii |
| Affiliation: | Centro Strumenti, University of Modena, 41100 Modena, Italy Department of Chemistry, University of Modena, 41100 Modena, Italy |
| Abstract: | Some Pd(II) and Pt(II) halide complexes with 2-bromo- and 2-chloro-1,3,4-thiadiazoles have been prepared and characterized by electronic, NMR, Raman and IR spectroscopy, and by thermogravimetric analysis and conductivity measurements. All of the complexes appear to have square-planar stereochemistry with MN2x2 (X = Cl or Br) chromophores. Two of them are present in the cis configuration while for all the others unambiguous trans configurations are observed. |
| Keywords: | Author to whom correspondence should be addressed. |
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