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Synthesis and efficient circularly polarized light emission of an optically active hyperbranched poly(fluorenevinylene) derivative
Authors:Yu Juin-Meng  Sakamoto Takeshi  Watanabe Kento  Furumi Seiichi  Tamaoki Nobuyuki  Chen Yun  Nakano Tamaki
Affiliation:Division of Biotechnology and Macromolecular Chemistry, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan.
Abstract:An optically active, hyperbranched poly(fluorenevinylene) derivative was synthesized by polymerization of (-)-2,4,7-tris(bromomethyl)-9-neomenthyl-9-pentylfluorene. A spin-coated film sample of the polymer exhibited efficient circularly polarized light (CPL) emission in the visible range of 400-700 nm on photo excitation even without annealing processes leading to chain ordering.
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