Properties of hollow molecules probed by single-photon double ionization |
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| Authors: | Lablanquie P Penent F Palaudoux J Andric L Selles P Carniato S Bučar K Zitnik M Huttula M Eland J H D Shigemasa E Soejima K Hikosaka Y Suzuki I H Nakano M Ito K |
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| Institution: | UPMC, Université Paris 06, LCPMR, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05, France. |
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| Abstract: | The formation of hollow molecules (with a completely empty K shell in one constituent atom) through single-photon core double ionization has been demonstrated using a sensitive magnetic bottle experimental technique combined with synchrotron radiation. Detailed properties are presented such as the spectroscopy, formation, and decay dynamics of the N(2)(2+) K(-2) main and satellite states and the strong chemical shifts of double K holes on an oxygen atom in CO, CO2, and O2 molecules. |
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