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Colorimetric response to anions by a "robust" copper(II) complex of a [9]aneN3 pendant arm derivative: CN- and I- selective sensing |
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| Authors: | Aguado Tetilla Marta Aragoni M Carla Arca Massimiliano Caltagirone Claudia Bazzicalupi Carla Bencini Andrea Garau Alessandra Isaia Francesco Laguna Antonio Lippolis Vito Meli Valeria |
| Institution: | Universidad de Zaragoza-CSIC, Departamento de Quimica Inorganica ICMA, Pedro Cerbuna 12, Zaragoza, 50009, Spain. |
| Abstract: | The 1 : 1 complex Cu(L)](BF(4))(2)·MeCN (1) of the tetradentate ligand 1-(2-quinolinylmethyl)-1,4,7-triazacyclononane (L) selectively changes its colour in the presence of CN(-) in H(2)O and MeCN (without undergoing decomplexation from the macrocyclic ligand). The same complex in MeCN assumes different colours in the presence of CN(-) or I(-). |
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