| 电化学现场X-射线衍射电解池及电极调节装置 |
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| 引用本文： | 陈昌国,辜敏,黄宗卿. 电化学现场X-射线衍射电解池及电极调节装置[J]. 分析化学, 1995, 23(2): 231-235 |
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| 作者姓名： | 陈昌国 辜敏 黄宗卿 |
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| 作者单位： | 重庆大学化工学院，中国科学院腐蚀科学开放研究实验室，重庆大学化工学院 重庆630044 |
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| 基金项目： | 厦门大学固体表面物理化学国家重点实验室的资助 |
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| 摘 要： | 设计了一种能在常规粉末衍射仪上通用的电化学现场X-射线衍射测定的电解池及其电极调节装置,实现了电极表面与窗片之间液层厚度的连续可调,精度达±2μm。理论计算与实测结果均表明液层厚与衍射峰强度和峰位之间存在定量关系。
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| 关 键 词： | X-射线衍射 电解池设计 液层厚度. |
In Situ X-Ray Diffraction Electrochemical Cell and Its , Electrode Adjust Device |
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| Chen Changguo,Gu Min. In Situ X-Ray Diffraction Electrochemical Cell and Its , Electrode Adjust Device[J]. Chinese Journal of Analytical Chemistry, 1995, 23(2): 231-235 |
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| Authors: | Chen Changguo Gu Min |
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| Abstract: | An in situ X-ray diffraction electrochemical cell and its electrode adjust device have been developed, which can be used on the conventional powder diffractometer. The thickness of the solution layer between the electrode surface and the window could be ad justed continuously in +2 um. The experiment and calculation have shown that the position and intensity of diffraction peak are quantitatively related to the thickness of the solution thin-layer. |
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| Keywords: | Electrochemical cell X-ray diffraction thin-layer thickness |
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