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Two‐Dimensional NMR Spectroscopy with Temperature‐Sweep
Authors:Wolfgang Bermel  Rupashree Dass  Klaus‐Peter Neidig  Krzysztof Kazimierczuk
Institution:1. Bruker BioSpin GmbH, Silberstreifen, 76287 Rheinstetten (Germany);2. Faculty of Chemistry, University of Warsaw, Pasteura 1, Warsaw, 02‐093 (Poland);3. Centre of New Technologies, University of Warsaw, Zwirki i Wigury 93, Warsaw, 02‐089 (Poland)
Abstract:Two‐dimensional nuclear magnetic resonance (NMR) spectroscopy is useful for studying temperature‐dependent effects on molecular structure. However, experimental time is usually long, because sampling is repeated at several temperatures. A novel solution to the problem is proposed, in which signal sampling is performed in parallel to the linear temperature‐sweep.
Keywords:compressed sensing  nmr spectroscopy  non‐uniform sampling  temperature‐sweep  time‐resolved spectroscopy
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