A spin trap ESR study of the regrouping of certain polyhalo-olefin radicals with 1,2 migration of chlorine |
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| Authors: | R G Gasanov I I Kandror M Ya Khorlina R Kh Freidlina |
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| Institution: | 1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
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| Abstract: | | 1. |
The 1,2-migration of chlorine in polyhalo-alkyl radicals of the RCH2CHCCl2X (X=H, F, CH3; R= CCl3, CHCl2).
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2-Methyl-2-nitroso-3-butanone is an effective trap for nonregrouping radicals, while 2-methyl-2-nitrosopropane is an equally effective trap for regrouping radicals of the RCH2CHClCClX type.
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