| Synthesis of Terpyridine Derivatives Containing β—Cyclodextrin |
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| 作者姓名： | XianHongYIN |
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| 作者单位： | DepartmentofChemistry,GuangxiUniversityforNationalities,Nanning530006 |
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| 基金项目： | 国家自然科学基金，Youth Foundation of Guangxi University for Nationalities |
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| 摘 要： | A novel β-cyclodextrin-based terpyridine derivatives has been prepared by the coupling of 4‘‘‘‘‘‘‘‘-(4“-bromomethyl phenyl)-2,2‘‘‘‘‘‘‘‘:6‘‘‘‘‘‘‘‘,2“-terpyridine with mono-6-hydroxy permethylated β-cyclodextrin.The cyclodextrin dimmer appending a 4‘‘‘‘‘‘‘‘-phenyl-2,2‘‘‘‘‘‘‘‘:6‘‘‘‘‘‘‘‘,2“-terpyridine spacer on the primary faces was synthesized by reaction of 4‘‘‘‘‘‘‘‘-phenyl-2,2‘‘‘‘‘‘‘‘:6‘‘‘‘‘‘‘‘,2“-terpyridine-6,6‘‘‘‘‘‘‘‘-dicarbonitrile with an excess of 6-deoxy-6-O-tosyl-β-cyclodextrin.
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| 关 键 词： | 三吡啶 衍生物 β－环糊精 包合物 合成 |
Synthesis of Terpyridine Derivatives Containing β-Cyclodextrin |
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| XianHongYIN.Synthesis of Terpyridine Derivatives Containing β-Cyclodextrin[J].Chinese Chemical Letters,2003,14(5):445-447. |
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| Authors: | Xian Hong YIN |
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| Abstract: | A novel b-cyclodextrin-based terpyridine derivatives has been prepared by the coupling of 4-(4-bromomethyl phenyl)- 2, 2:6, 2-terpyridine with mono-6-hydroxy permethylated b- cyclodextrin. The cyclodextrin dimmer appending a 4-phenyl-2,2:6,2- terpyridine spacer on the primary faces was synthesized by reaction of 4-phenyl-2,2:6,2-terpyridine-6,6-dicarbonitrile with an excess of 6-deoxy-6-O-tosyl-b-cyclodextrin. |
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| Keywords: | Cyclodextrin terpyridine synthesis |
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