Catalytic enantioselective synthesis of vicinal dialkyl arrays |
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| Authors: | van Zijl Anthoni W Szymanski Wiktor López Ferrnando Minnaard Adriaan J Feringa Ben L |
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| Affiliation: | Stratingh Institute for Chemistry, Faculty of Mathematics and Natural Sciences, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands. |
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| Abstract: | With a consecutive "asymmetric allylic alkylation (AAA)/cross-metathesis (CM)/conjugate addition (CA)" protocol it is possible to synthesize either stereoisomer of compounds containing a vicinal dialkyl array with excellent stereoselectivity. The versatility of this protocol in natural product synthesis is demonstrated in the preparation of the ant pheromones faranal and lasiol. |
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