Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate |
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| Authors: | Swiderski Konrad McLean Andrew Gordon Charles M Vaughan D H |
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| Institution: | Department of Chemistry & Chemical Engineering, University of Paisley, Paisley, Scotland, UK PA1 2BE. |
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| Abstract: | The bimolecular rate constant for solvent displacement, k(2), from (C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, bmim]PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane. |
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