Equilibrium differential capacitance and electrocapillary curves within the framework of a generalized model of the surface layer |
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Authors: | B. B. Damaskin |
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Affiliation: | (1) Moscow State University, Vorob’evy Gory, Moscow, 119992, Russia |
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Abstract: | Equations that describe the equilibrium differential capacitance C and the interface tension of an electrode subjected to the adsorption of organic molecules under the conditions where this adsorption strictly follows a generalized model of the surface layer are derived. Using the developed programs, the dependences of C on the electrode potential φ are calculated at different concentrations of the organic substance. Based on these C vs. φ curves, a set of effective parameters is obtained. With these parameters, the capacitance curves can best be described by the model of two parallel capacitors combined with the Frumkin isotherm. |
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Keywords: | generalized model of surface layer differential capacitance electrocapillary curves adsorption of organic molecules |
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