Wasserphotolyse mit Hilfe von funktionellen Tris-(2,2′-bipyridin)ruthenium(II)-Komplexen期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Wasserphotolyse mit Hilfe von funktionellen Tris-(2,2′-bipyridin)ruthenium(II)-Komplexen

Authors:	W. Nußbaumer H. Gruber G. F. Greber

Affiliation:	(1) Institut für Chemische Technologie organischer Stoffe, Technische Universität Wien, A-1060 Wien, Österreich

Abstract:	19 Tris(2,2-bipyridyl)ruthenium(II) complexes with functional groups were synthesized and investigated as sensitizers in photochemical hydrogen production by visible light with the four component system Ru(bipy)₃²⁺, methylviologen, ethylenediamintetraacetic acid and colloidal platinum ruthenium-bipyridine complexes with electron accepting groups, e.g. halogen or carboxylate were found to be most effective in hydrogen generation. Herrn Prof. Dr. mult.Viktor Gutmann zum 65. Geburtstag gewidmet.

Keywords:	Water photolysis Tris(2,2 /content/n55135h8801m1565/xxlarge8242.gif" alt=" prime" align=" BASELINE" BORDER=" 0" >-bipyridyl)ruthenium(II) complexes with functional groups Tris(2,2 /content/n55135h8801m1565/xxlarge8242.gif" alt=" prime" align=" BASELINE" BORDER=" 0" >-bipyridyl)ruthenium(II) complexes as sensitizers
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