Catalysis by rhodium complexes bearing pyridine ligands: Mechanistic aspects |
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| Authors: | Alvaro J Pardey Clementina Longo |
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| Institution: | 1. Centro de Equilibrios en Solución, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas, Venezuela;2. Centro de Investigación y Desarrollo de Radiofármacos, Facultad de Farmacia, Universidad Central de Venezuela, Caracas, Venezuela |
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| Abstract: | The present review describes several examples of the use of soluble and immobilized complexes of rhodium with pyridine ligands as catalysts. Examples include the water-gas shift reaction, the carbonylation of methanol, the reduction of nitroarenes, the hydrocarboxylation and oligomerization of CO/ethylene, the hydrocarbonylation of 1-hexene, the hydroesterification and hydroformylation–acetalization of 1-hexene, the hydrodechlorination of dichloroethane, the carbonylation of naphtha and the hydrogenation and hydroformylation of alkenes. |
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