Immobilized ruthenium complexes and aspects of their reactivity |
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| Authors: | Elia Tfouni Fabio Gorzoni Doro Anderson Jesus Gomes Roberto Santana da Silva Gustavo Metzker Patricia Graça Zanichelli Benini Douglas Wagner Franco |
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| Institution: | 1. Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirtão Preto, Universidade de São Paulo, Av. dos Bandeirantes, 3900, 14040-901 Ribeirão Preto, SP, Brazil;2. Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Av. do Café s/n, 14040-903 Ribeirão Preto, SP, Brazil;3. Instituto de Química de São Carlos, Universidade de São Paulo, Av. Trabalhador São-carlense, 400, 13566-590 São Carlos, SP, Brazil |
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| Abstract: | Methodologies for the immobilization and characterization of ruthenium complexes into/onto functionalized silica gel, zeolites, polymers, dendrimers, sol–gel, nano and microparticles are described. The corresponding spectroscopic, electrochemical, and photochemical properties as well as chemical reactivities are used for their characterization and study. Comparison between the reactivities of immobilized and in solution species is presented. Some biological applications are also described. |
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