Olefin oligomerization,homopolymerization and copolymerization by late transition metals supported by (imino)pyridine ligands |
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Authors: | Claudio Bianchini Giuliano Giambastiani Lapo Luconi Andrea Meli |
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Institution: | Istituto di Chimica dei Composti OrganoMetallici – Consiglio Nazionale delle Ricerche (ICCOM-CNR), via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze, Italy |
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Abstract: | In this review, the key advances achieved over more than 10 years on the design and development of (imino)pyridyl transition metal complexes as catalyst precursors for the transformation of ethylene, higher α-olefins and cyclic olefins into either linear/branched homopolymers or oligomers are highlighted. Particular attention has been paid to the relationships between the catalytic activity exhibited by the catalysts and their electronic and geometrical structure. |
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