Prediction of excess thermodynamic functions and activity coefficients of some polymeric liquid mixtures using a new equation of state |
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Authors: | Elaheh K. Goharshadi Maryam Imani Rayhaneh Rahimi-Zarei Fahimeh Razghandi Maryam Abareshi Ali R. Berenji |
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Affiliation: | 1. Dept. of Chemistry, Ferdowsi University of Mashhad, Mashhad 91779, Iran;2. Chemistry & Chemical Engineering Research Institute of Iran, Tehran 14335-186, Iran;3. Dept. of Chemistry, Faculty of Basic Sciences, Tarbiat Modares University, 14115-335 Tehran, Iran |
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Abstract: | In this work, the excess thermodynamic properties, namely excess molar Gibbs energy, excess molar enthalpy, excess molar entropy, excess molar internal energy, and excess molar Helmholtz energy for four polymer mixtures and blends at different temperatures, pressures, and compositions have been calculated using the GMA equation of state. We have also calculated the activity coefficient for these polymeric mixtures using the GMA equation of state. The values of statistical parameters between experimental and calculated properties show the ability of this equation of state in reproducing and predicting the excess thermodynamic functions and activity coefficients for studied polymeric mixtures. |
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