Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene |
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| Authors: | Yan Zhang Jianbo Wang |
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| Affiliation: | 1. Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;2. State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | This paper reviews the most recent development of [2,3]-sigmatropic rearrangement of sulfur ylide generated from the reaction of sulfide with metal carbene. The metal carbene was formed from decomposition of diazo compounds catalyzed by transition metal complexes such as Cu(I) and Rh(II). |
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