Rate constants for reactions of hydroxyl radicals with nitromethane and methyl nitrite vapours at 292 K |
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| Authors: | I.M. Campbell K. Goodman |
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| Affiliation: | School of Chemistry, The University, Leeds, LS2 9JT, UK |
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| Abstract: | The variations of yields of CO2 from the gas phase H2O2 + NO2 + CO chain reaction system with added nitromethane or methyl nitrite have given rate constants for reactions of OH radicals with these substrates. At 292 K these are (5.5 ± 0.6) × 108 and (8.0 ± 1.1) × 108 dm3 mol?1 s?1 respectively. |
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